Is Ba(OH)2 a Strong or Weak Base? (And Why?)

Ba(OH)2 is a strong base. 1 When dissolved in water, it completely dissociates into barium ions (Ba2+) and hydroxide ions (OH-). This full dissociation leads to a high concentration of hydroxide ions in the solution, making it a strong base with a high pH value.

Well, this was just a simple answer. But there are few more things to know about this topic which will make your concept super clear.

So let’s dive right into it.

Key Takeaways: Is Ba(OH)2 a Strong or Weak Base?

  • Ba(OH)2 is a strong base due to its ability to completely dissociate into hydroxide ions (OH-) and barium ions (Ba2+) in water, leading to a high concentration of OH- ions and a strongly basic solution.
  • In contrast, weak bases only partially dissociate in water, resulting in a lower concentration of hydroxide ions and a weaker basic solution.
  • The strong basic nature of Ba(OH)2 makes it useful as a chemical reagent, a precursor in the production of other barium compounds, a water treatment agent, and for neutralizing acidic waste.

Why is Ba(OH)2 a strong base?

Barium hydroxide (Ba(OH)2) is considered a strong base due to its ability to dissociate completely into hydroxide ions (OH-) and barium ions (Ba2+) in an aqueous solution. 

When Ba(OH)2 is dissolved in water, it undergoes a dissociation reaction:

Ba(OH)2 (s) → Ba2+(aq) + 2OH(aq)

The hydroxide ions released by the dissociation of Ba(OH)2 are responsible for its strong basic properties. These hydroxide ions readily accept protons (H+) from water molecules, leading to an increase in hydroxide ion concentration in the solution. The presence of a high concentration of hydroxide ions in the solution makes the solution strongly basic.

Strong bases are substances that dissociate almost completely into hydroxide ions and cations (metal ions) when dissolved in water. In contrast, weak bases only partially dissociate, resulting in a lower concentration of hydroxide ions in the solution. 2 The strength of a base is related to the extent of its dissociation in water and its ability to generate hydroxide ions.

Barium hydroxide is not commonly encountered in everyday situations due to its strong basic nature and potential hazards. It is highly corrosive and can cause severe burns if it comes into contact with skin. 3 4 Therefore, it is essential to handle it with great care and adhere to safety guidelines when working with such strong bases.

How does the dissociation of Ba(OH)2 differ from that of a weak base?

Here is a table for comparison of the dissociation of Ba(OH)2 (a strong base) and a generic weak base represented as “B”.

Dissociation in WaterBa(OH)2 (Strong Base)Weak Base (B)
Chemical EquationBa(OH)2 (s) → Ba2+(aq) + 2 OH(aq)B(aq) ⇌ B+(aq) + OH(aq)
Degree of DissociationAlmost complete dissociation 5Partial dissociation 2 6
Hydroxide Ion FormationProduces a high concentration of OH- ions 7 8 9Produces a low concentration of OH- ions 10
pH of the SolutionResults in a strongly basic solution with a high pH 11Results in a weakly basic solution with a moderate pH 12
ConductivityHigh conductivity due to a large number of ions 13Lower conductivity due to fewer ions 14
ExamplesBarium hydroxide (Ba(OH)2)Ammonia (NH3), Acetic acid (CH3COOH)

In the table above, “B” represents a generic weak base. It is important to note that the dissociation reaction for weak bases is represented with a double arrow (⇌) to indicate that it is an equilibrium reaction, and the dissociation is only partial.

Applications of Ba(OH)2 based on its strong basic nature

Due to its strong basic nature, barium hydroxide (Ba(OH)2) has various applications in different industries and chemical processes. Some of the key applications are as follows:

  1. Chemical Reagent: Ba(OH)2 is commonly used as a strong base in chemical laboratories and industries to carry out various chemical reactions. Its ability to neutralize acidic substances makes it valuable in titrations and analytical chemistry. 15
  2. Manufacture of Other Barium Compounds: Ba(OH)2 serves as a precursor in the production of other barium compounds. For example, it is used to produce barium carbonate (BaCO3) and barium chloride (BaCl2).
  3. Water Treatment: Ba(OH)2 can be used in water treatment processes to remove certain impurities and ions from water. It can help in the precipitation of metals, such as iron and manganese, as their hydroxide precipitates. 16
  4. Neutralization of Acidic Waste: Industries generate acidic waste during various processes. Ba(OH)2 can be used to neutralize this acidic waste before disposal, preventing environmental damage. 17
  5. Synthesis of Organic Compounds: In organic synthesis, Ba(OH)2 can be used as a strong base in various reactions, such as the hydrolysis of esters and nitriles. 18
  6. Catalysis: In some chemical reactions, Ba(OH)2 can act as a catalyst, accelerating the reaction rate without being consumed in the process. 19 20
  7. Concrete Additive: In the construction industry, small amounts of Ba(OH)2 can be used as an additive to concrete to improve its strength and durability. 21

Further reading

Is KOH (Potassium Hydroxide) a Strong or Weak Base?
Is NH3 (Ammonia) a Strong Base or Weak Base?
Is NaOH (Sodium Hydroxide) a Strong or Weak Base?
Is Calcium Hydroxide [Ca(OH)2] a Strong Base?
Is LiOH a Strong Base?

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References

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  2. Weak acid-base equilibria (article) | Khan Academy. (n.d.). Khan Academy. https://www.khanacademy.org/science/chemistry/acids-and-bases-topic/copy-of-acid-base-equilibria/a/weak-acid-base-equilibria
  3. Westliberty.edu https://westliberty.edu/health-and-safety/files/2012/08/Barium-Hydroxide.pdf
  4. Sigmaaldrich.com https://www.sigmaaldrich.com/IN/en/sds/SIGALD/217573
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  7. Strong base solutions (video) | Khan Academy. (n.d.). Khan Academy. https://www.khanacademy.org/science/ap-chemistry-beta/x2eef969c74e0d802:acids-and-bases/x2eef969c74e0d802:ph-and-poh-of-strong-acids-and-bases/v/strong-base-solutions
  8. Acid-Base Titration: Calculating pH, Strength, and Concentration – Concept | Lab: Chemistry | JoVE. (n.d.). Acid-Base Titration: Calculating pH, Strength, and Concentration – Concept | Lab: Chemistry | JoVE. https://www.jove.com/science-education/11150/acid-and-base-concentrations
  9. Sanjac.edu https://www.sanjac.edu/sites/default/files/Acid-Base%2520Properties%2520of%2520Salt%2520Solutions_0.pdf
  10. Weak base equilibria (video) | Khan Academy. (n.d.). Khan Academy. https://www.khanacademy.org/science/ap-chemistry-beta/x2eef969c74e0d802:acids-and-bases/x2eef969c74e0d802:weak-acid-and-base-equilibria/v/weak-base-equilibria
  11. L. (n.d.). Strength of Bases – Introductory Chemistry. Strength of Bases – Introductory Chemistry. https://uen.pressbooks.pub/introductorychemistry/chapter/strength-of-bases/
  12. Weak base – Wikipedia. (2018, March 23). Weak Base – Wikipedia. https://en.wikipedia.org/wiki/Weak_base
  13. Elmhurst.edu http://chemistry.elmhurst.edu/vchembook/185strength.html
  14. Acid and Base Strength. (2013, October 2). Chemistry LibreTexts. https://chem.libretexts.org/Bookshelves/Physical_and_Theoretical_Chemistry_Textbook_Maps/Supplemental_Modules_(Physical_and_Theoretical_Chemistry)/Acids_and_Bases/Ionization_Constants/Acid_and_Base_Strength
  15. Anderson, G., Fahey, C., MacDonald, J., Richards, A., Sauer, S. S., Haarlem, J. V., & Wegman, D. (n.d.) 16.6 Titrations and Neutralization Calculations – Enhanced Introductory College Chemistry. https://ecampusontario.pressbooks.pub/enhancedchemistry/chapter/titrations/
  16. Bologo, V., Maree, J., & Carlsson, F. (n.d.). Application of Magnesium Hydroxide and Barium Hydroxide for the Removal of Metals and Sulphate From Mine Water. http://www.scielo.org.za/scielo.php?script=sci_arttext&pid=S1816-79502012000100004
  17. CN103936190A – Barium hydroxide treatment method with zero discharging of lead-acid storage battery wastewater – Google Patents. (2014, April 2) https://patents.google.com/patent/CN103936190A/en
  18. Barium hydroxide – Wikipedia. (2014, April 2). Barium Hydroxide – Wikipedia. https://en.wikipedia.org/wiki/Barium_hydroxide
  19. Canadian Science Publishing. https://cdnsciencepub.com/doi/pdf/10.1139/v87-195
  20. Sinisterra, J. V., Garcia-Blanco, F., Iglesias, M., & Marinas, J. M. (1985, September). Ba(OH)2 as catalyst in organic reactions: I. Nature of active sites in the michael addition. Reaction Kinetics and Catalysis Letters, 27(2), 263–267. https://doi.org/10.1007/bf02070454
  21. Core.ac.uk https://core.ac.uk/download/pdf/228200918.pdf

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