Benzoic acid (C6H5COOH) is sparingly soluble in cold water. 1 The solubility of benzoic acid in cold water is very less, but its solubility significantly increases in hot water. 2 3 4
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Key Takeaways: Is Benzoic Acid Soluble in Water?
- Benzoic acid (C6H5COOH) is sparingly soluble in cold water.
- The solubility of benzoic acid in water significantly increases with temperature, with higher solubility observed in hot water.
- Benzoic acid is a polar compound and can dissolve in other polar solvents such as ethanol, methanol, acetone, diethyl ether, and chloroform.
Solubility of benzoic acid in water
Benzoic acid (C6H5COOH) exhibits sparing solubility in cold water. However, its solubility markedly increases in hot water, indicating a temperature-dependent solubility behavior. 5
The solubility of benzoic acid is affected by the intermolecular forces between its molecules and the water molecules. In cold water, the kinetic energy of the water molecules is relatively low, limiting their ability to break the strong intermolecular forces present in the benzoic acid crystals. As a result, only a small amount of benzoic acid dissolves in cold water.
In hot water, the increased temperature leads to higher kinetic energy, 6 enabling water molecules to overcome the intermolecular forces of the solid benzoic acid more effectively.
This allows a larger number of benzoic acid molecules to escape from the solid lattice and enter the water, resulting in a significant increase in its solubility.
In summary, the solubility of benzoic acid in water is dependent on temperature, with higher solubility observed in hot water due to increased molecular motion and more effective disruption of the solid lattice.
Can benzoic acid dissolve in other solvents?
Yes, benzoic acid can dissolve in other solvents besides water. Benzoic acid is a polar compound, meaning it has a partial positive and partial negative charge within its molecule. 7 This polarity allows it to interact with other polar solvents. Some common solvents in which benzoic acid is soluble include ethanol, methanol, acetone, diethyl ether, and chloroform. 8
In general, solvents with polar characteristics tend to dissolve benzoic acid more readily due to the attractive forces between the polar solute and solvent molecules.
These solvents provide an environment where the polar benzoic acid molecules can interact and disperse, resulting in their dissolution. The solubility of benzoic acid in these solvents will depend on factors such as temperature, the specific solvent’s polarity, and the concentration of benzoic acid.
It’s worth noting that nonpolar solvents, such as hexane or toluene, are typically not effective at dissolving benzoic acid due to the lack of polarity in these solvents.
The polarity mismatch prevents sufficient interaction between the solute and solvent molecules, limiting the solubility of benzoic acid in nonpolar solvents.
Further reading
Why is Acetic Acid Soluble in Water?
Why is Na2SO4 (Sodium Sulfate) Soluble in Water?
Why is Na2CO3 (Sodium Carbonate) Soluble in Water?
Are Alcohols Soluble in Water?
Why is Na2S Soluble in Water?
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References
- P. (n.d.). Benzoic Acid. Benzoic Acid | C6H5COOH | CID 243 – PubChem. https://pubchem.ncbi.nlm.nih.gov/compound/243
- Donell, M. (2023, January 31). Why Is Benzoic Acid More Soluble In Hot Water? Ozmo.io. https://www.ozmo.io/why-is-benzoic-acid-more-soluble-in-hot-water/
- Benzoic acid. (n.d.). Benzoic Acid. http://chemister.ru/Database/properties-en.php?dbid=1&id=679
- Solubilities of Inorganic and Organic Compounds. (n.d.). Google Books. https://books.google.com/books/about/Solubilities_of_Inorganic_and_Organic_Co.html?id=k2e5AAAAIAAJ
- Why Is Benzoic Acid Poorly Soluble In Cold Water? (2016, October 3). https://www.worldofchemicals.com/523/chemistry-articles/why-is-benzoic-acid-poorly-soluble-in-cold-water.html
- Office of Marketing and Communications, G. E. (n.d.). Temperature and Water Molecules. Temperature and Water Molecules | Physics Van | UIUC. https://van.physics.illinois.edu/ask/listing/1497
- Polarity & Solubility of Benzoic acid. (2022, September 14). YouTube. https://www.youtube.com/watch?v=GkUUkdS38Vs
- Benzoic acid – Wikipedia. (2018, October 24). Benzoic Acid – Wikipedia. https://en.wikipedia.org/wiki/Benzoic_acid
