N2H2 Lewis Structure in 6 Steps (With Images)

So you have seen the above image by now, right?

Let me explain the above image in short.

N2H2 lewis structure has a double bond between the two Nitrogen atoms (N) and a single bond between the Nitrogen atom (N) and Hydrogen atom (H). There are 2 lone pairs on both the Nitrogen atoms (N).

If you haven’t understood anything from the above image of N2H2 lewis structure, then just stick with me and you will get the detailed step by step explanation on drawing a lewis structure of N2H2.

So let’s move to the steps of drawing the lewis structure of N2H2.

Steps of drawing N2H2 lewis structure

Step 1: Find the total valence electrons in N2H2 molecule

In order to find the total valence electrons in N2H2 molecule, first of all you should know the valence electrons present in nitrogen atom as well as hydrogen atom.
(Valence electrons are the electrons that are present in the outermost orbit of any atom.)

Here, I’ll tell you how you can easily find the valence electrons of nitrogen as well as hydrogen using a periodic table.

Total valence electrons in N2H2 molecule

→ Valence electrons given by nitrogen atom:

Nitrogen is a group 15 element on the periodic table. ^[1] Hence the valence electrons present in nitrogen is 5.

You can see the 5 valence electrons present in the nitrogen atom as shown in the above image.

→ Valence electrons given by hydrogen atom:

Hydrogen is group 1 element on the periodic table. ^[2] Hence the valence electron present in hydrogen is 1.

You can see that only 1 valence electron is present in the hydrogen atom as shown in the above image.

Hence, 

Total valence electrons in N2H2 molecule = valence electrons given by 2 nitrogen atom + valence electrons given by 2 hydrogen atoms = 5(2) + 1(2) = 12.

Step 2: Select the central atom

For selecting the center atom, you have to remember that the atom which is less electronegative remains at the center.

(Remember: If hydrogen is present in the given molecule, then always put hydrogen outside.)

Now here the given molecule is N2H2 (dinitrogen dihydride) and it contains nitrogen atom (N) and hydrogen atoms (H).

You can see the electronegativity values of nitrogen atom (N) and hydrogen atom (H) in the above periodic table.

If we compare the electronegativity values of nitrogen (N) and hydrogen (H) then the hydrogen atom is less electronegative. But as per the rule we have to keep hydrogen outside.

So here both the nitrogen atoms (N) are the center atom and the hydrogen atoms (H) are the outside atoms.

Step 3: Connect each atoms by putting an electron pair between them

Now in the N2H2 molecule, you have to put the electron pairs between the nitrogen-nitrogen atoms and between the nitrogen-hydrogen atoms.

This indicates that these atoms are chemically bonded with each other in a N2H2 molecule.

Step 4: Make the outer atoms stable. Place the remaining valence electrons pair on the central atom.

Now in this step, you have to check the stability of the outer atoms.

Here in the sketch of N2H2 molecule, you can see that the outer atoms are 2 hydrogen atoms and 1 nitrogen atom.

These hydrogen atoms and nitrogen atom are forming a duplet and octet respectively and hence they are stable.

Also, in step 1 we have calculated the total number of valence electrons present in the N2H2 molecule.

The N2H2 molecule has a total 12 valence electrons and out of these, only 10 valence electrons are used in the above sketch.

So the number of electrons which are left = 12 – 10 = 2.

You have to put these 2 electrons on the nitrogen atom in the above sketch of N2H2 molecule.

Now let’s proceed to the next step.

Step 5: Check the octet on the central atom. If it does not have octet, then convert the lone pair into a double bond or triple bond.

In this step, you have to check whether the central nitrogen atoms (N) are stable or not.

In order to check the stability of the central nitrogen (N) atoms, we have to check whether they are forming an octet or not.

Unfortunately, one of the nitrogen atoms is not forming an octet here. The left side nitrogen has only 6 electrons and it is unstable.

Now to make this nitrogen atom stable, you have to shift the electron pair from the outer nitrogen atom so that the central (left side) nitrogen atom can have 8 electrons (i.e octet).

After shifting this electron pair, the central nitrogen atom will get 2 more electrons and thus its total electrons will become 8.

You can see from the above picture that both the nitrogen atoms are forming an octet as they have 8 electrons.

Now let’s proceed to the final step to check whether the above lewis structure is stable or not.

Step 6: Check the stability of lewis structure

Now you have come to the final step in which you have to check the stability of lewis structure of N2H2.

The stability of lewis structure can be checked by using a concept of formal charge.

In short, now you have to find the formal charge on nitrogen (N) atoms as well as hydrogen (H) atoms present in the N2H2 molecule.

For calculating the formal charge, you have to use the following formula;

Formal charge = Valence electrons – (Bonding electrons)/2 – Nonbonding electrons

You can see the number of bonding electrons and nonbonding electrons for each atom of N2H2 molecule in the image given below.

For Nitrogen (N) atom:
Valence electrons = 5 (because nitrogen is in group 15)
Bonding electrons = 6
Nonbonding electrons = 2

For Hydrogen (H) atom:
Valence electron = 1 (because hydrogen is in group 1)
Bonding electrons = 2
Nonbonding electrons = 0

Formal charge	=	Valence electrons	–	(Bonding electrons)/2	–	Nonbonding electrons
N	=	5	–	6/2	–	2	=	0
H	=	1	–	2/2	–	0	=	0

From the above calculations of formal charge, you can see that the nitrogen (N) atoms as well as hydrogen (H) atoms have a “zero” formal charge.

This indicates that the above lewis structure of N2H2 is stable and there is no further change in the above structure of N2H2.

In the above lewis dot structure of N2H2, you can also represent each bonding electron pair (:) as a single bond (|). By doing so, you will get the following lewis structure of N2H2.

I hope you have completely understood all the above steps.

For more practice and better understanding, you can try other lewis structures listed below.

Try (or at least See) these lewis structures for better understanding:

HBr lewis structure	N2H4 lewis structure
CH3NH2 lewis structure	SiO2 lewis structure
SiH4 lewis structure	ClO4- lewis structure