So you have seen the above image by now, right?
Let me explain the above image in short.
SeO3 lewis structure has a Selenium atom (Se) at the center which is surrounded by three Oxygen atoms (O). There are 3 double bonds between the Selenium atom (Se) and each Oxygen atom (O). There are 2 lone pairs on all three Oxygen atoms (O).
If you haven’t understood anything from the above image of SeO3 lewis structure, then just stick with me and you will get the detailed step by step explanation on drawing a lewis structure of SeO3.
So let’s move to the steps of drawing the lewis structure of SeO3.
Steps of drawing SeO3 lewis structure
Step 1: Find the total valence electrons in SeO3 molecule
In order to find the total valence electrons in a SeO3 molecule, first of all you should know the valence electrons present in selenium atom as well as oxygen atom.
(Valence electrons are the electrons that are present in the outermost orbit of any atom.)
Here, I’ll tell you how you can easily find the valence electrons of selenium as well as oxygen using a periodic table.
Total valence electrons in SeO3 molecule
→ Valence electrons given by selenium atom:
Selenium is a group 16 element on the periodic table. [1] Hence the valence electrons present in selenium is 6.
You can see the 6 valence electrons present in the selenium atom as shown in the above image.
→ Valence electrons given by oxygen atom:
Oxygen is group 16 element on the periodic table. [2] Hence the valence electrons present in oxygen is 6.
You can see the 6 valence electrons present in the oxygen atom as shown in the above image.
Hence,
Total valence electrons in SeO3 molecule = valence electrons given by 1 selenium atom + valence electrons given by 3 oxygen atoms = 6 + 6(3) = 24.
Step 2: Select the central atom
For selecting the center atom, you have to remember that the atom which is less electronegative remains at the center.
Now here the given molecule is SeO3 and it contains selenium atom (Se) and oxygen atoms (O).
You can see the electronegativity values of selenium atom (Se) and oxygen atom (O) in the above periodic table.
If we compare the electronegativity values of selenium (Se) and oxygen (O) then the selenium atom is less electronegative.
So here the selenium atom (Se) is the center atom and the oxygen atoms (O) are the outside atoms.
Step 3: Connect each atoms by putting an electron pair between them
Now in the SeO3 molecule, you have to put the electron pairs between the selenium atom (Se) and oxygen atoms (O).
This indicates that the selenium (Se) and oxygen (O) are chemically bonded with each other in a SeO3 molecule.
Step 4: Make the outer atoms stable
Now in this step, you have to check the stability of the outer atoms.
Here in the sketch of SeO3 molecule, you can see that the outer atoms are oxygen atoms.
These outer oxygen atoms are forming an octet and hence they are stable.
Also, in step 1 we have calculated the total number of valence electrons present in the SeO3 molecule.
The SeO3 molecule has a total 24 valence electrons and all these valence electrons are used in the above sketch of SeO3.
Hence there are no remaining electron pairs to be kept on the central atom.
So now let’s proceed to the next step.
Step 5: Check the octet on the central atom. If it does not have octet, then shift the lone pair to form a double bond or triple bond.
In this step, you have to check whether the central selenium atom (Se) is stable or not.
In order to check the stability of the central selenium (Se) atom, we have to check whether it is forming an octet or not.
Unfortunately, the selenium atom is not forming an octet here. Selenium has only 6 electrons and it is unstable.
Now to make this selenium atom stable, you have to shift the electron pair from the outer oxygen atom so that the selenium atom can have 8 electrons (i.e octet).
After shifting this electron pair, the central selenium atom will get 2 more electrons and thus its total electrons will become 8.
You can see from the above picture that the selenium atom is forming an octet as it has 8 electrons.
Now let’s proceed to the final step to check whether the lewis structure of SeO3 is stable or not.
Step 6: Check the stability of lewis structure
Now you have come to the final step in which you have to check the stability of lewis structure of SeO3.
The stability of lewis structure can be checked by using a concept of formal charge.
In short, now you have to find the formal charge on selenium (Se) atom as well as oxygen (O) atoms present in the SeO3 molecule.
For calculating the formal charge, you have to use the following formula;
Formal charge = Valence electrons – (Bonding electrons)/2 – Nonbonding electrons
You can see the number of bonding electrons and nonbonding electrons for each atom of SeO3 molecule in the image given below.
For Selenium (Se) atom:
Valence electrons = 6 (because selenium is in group 16)
Bonding electrons = 8
Nonbonding electrons = 0
For double bonded Oxygen (O) atom:
Valence electrons = 6 (because oxygen is in group 16)
Bonding electrons = 4
Nonbonding electrons = 4
For single bonded Oxygen (O) atom:
Valence electrons = 6 (because oxygen is in group 16)
Bonding electrons = 2
Nonbonding electrons = 6
Formal charge | = | Valence electrons | – | (Bonding electrons)/2 | – | Nonbonding electrons | ||
Se | = | 6 | – | 8/2 | – | 0 | = | +2 |
O (double bonded) | = | 6 | – | 4/2 | – | 4 | = | 0 |
O (single bonded, 1st) | = | 6 | – | 2/2 | – | 6 | = | -1 |
O (single bonded, 2nd) | = | 6 | – | 2/2 | – | 6 | = | -1 |
From the above calculations of formal charge, you can see that the selenium (Se) atom has +2 charge and both the single bonded oxygen (O) atoms have -1 charges.
Because of this reason, the above obtained lewis structure of SeO3 is not stable.
So we have to minimize these charges by shifting the electron pairs towards the selenium atom.
After shifting the electron pairs from oxygen atom to selenium atom, the lewis structure of SeO3 becomes more stable.
In the above lewis dot structure of SeO3, you can also represent each bonding electron pair (:) as a single bond (|). By doing so, you will get the following lewis structure of SeO3.
I hope you have completely understood all the above steps.
For more practice and better understanding, you can try other lewis structures listed below.
Try (or at least See) these lewis structures for better understanding:
CHF3 Lewis Structure | BrO4- Lewis Structure |
NO2F Lewis Structure | XeOF4 Lewis Structure |
ICl Lewis Structure | H2SO3 Lewis Structure |
Jay is an educator and has helped more than 100,000 students in their studies by providing simple and easy explanations on different science-related topics. He is a founder of Pediabay and is passionate about helping students through his easily digestible explanations.
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